Two new mono- and dinuclear Cu(II)

Two new mono- and dinuclear Cu(II) complexes,
namely [CuL1]
0.5H2O (1) and [(Cu2(L2)2)(DMF)]

0.5DMF (2) (H2L1 = 1,2-bis{[(Z)-(3-methyl-5-oxo-1-phenyl-
1H-pyrazolidin-4(4H)-yl)(phenyl)]methylene-aminooxy}
ethane; H2L2 = 1,3-bis{[(Z)-(3-methyl-5-oxo-1-phenyl-1Hpyrazolidin-
4(4H)-yl)(phenyl)] methyleneaminooxy}propane),
have been synthesized and characterized by X-ray
crystallography.

結果 (中文) 1:

两个新单和双核铜配合物，即 [CuL1] 0.5H2O (1) 和 [(Cu2(L2)2)(DMF)](2) 0.5DMF (H2L1 = 1,2-bis{[(Z)-(3-methyl-5-oxo-1-phenyl-1H-pyrazolidin-4(4H)-yl)(phenyl)] 亚甲基-氨基氧基}乙烷;H2L2 = 1,3-bis{[(Z)-(3-methyl-5-oxo-1-phenyl-1Hpyrazolidin-4(4H)-yl)(phenyl)] methyleneaminooxy} 丙烷)，被合成和表征晶体学。

結果 (中文) 3:

两个新的单、双核铜（II）配合物，
即[ Cul1 ]
0.5H2O（1）和[（Cu2（L2）2）（DMF）]

0.5dmf（2）（H2L1 =双{ [（Z）-（3-methyl-5-oxo-1-phenyl -
1h-pyrazolidin-4（4H）-基）（苯基）]亚甲基氨基氧基}
乙烷；H2L2 = 1,3-二{ [（Z）-（3-methyl-5-oxo-1-phenyl-1hpyrazolidin -
4（4H）-基）（苯基）] methyleneaminooxy }丙烷），
的合成和表征通过X-射线晶体学是
。