The ITO/TiO2 film was immersed in 0

The ITO/TiO2 film was immersed in 0.1 M ZnCl2 complexed with ammonium hydroxide and hydrogen peroxide for a period of 25 s. Excess ammonium hydroxide solution was used to
control the pH of the ZnCl2 solution to 14. Addition of the ammonium hydroxide solution to the ZnCl2 resulted in the formation of a Zn(OH)2 precipitate, but this redissolved in excess ammonium hydroxide to form the tetra-amine zinc complex. Then, the substrate was immersed in distilled water at 90 °C. High temperatures promoted the adherence of the ZnO film. In the first preparative stage, the ammonia-zinc ions complex was adsorbed onto the substrate surface, and in the second preparative stage, the hydroxide of the anion precursor solution was adsorbed onto the surface and reacted with the adsorbed zinc species to yield zinc hydroxide, which in turn was converted into ZnO. There were several insoluble zinc species present in a reaction bath containing OH-, NH3, and Zn2+ ions.

結果 (中文) 1:

ITO/TiO2 薄膜被沉浸在 0.1 M ZnCl2 络合与氢氧化铵和过氧化氢为期 25 美国过剩氢氧化铵溶液为习惯控制到 14 ZnCl2 溶液的 ph 值。氢氧化铵液到 ZnCl2 导致形成的 Zn (OH) 2 沉淀，但这再溶解在过量的铵氢氧化钠 tetra 胺锌配合物。然后，承印物上沉浸在蒸馏水在 90 ° c。高温促进 ZnO 薄膜的遵守。在第一的准备阶段，复杂的氨锌离子被吸附到衬底表面，并在第二的准备阶段，阴离子前驱体溶液的氢氧化吸附到表面吸附的锌物种产生氢氧化锌，再被转化成氧化锌的反应。有几个不溶锌物种存在于一种含 OH-、 NH3、 和 Zn2 + 离子的反应液。

結果 (中文) 3:

ITO／TiO2膜浸渍在0.1 M氯化锌与一段25秒的过量的氢氧化铵溶液氨水和过氧化氢用于控制氯化锌溶液的pH为14。在氢氧化铵溶液氯化锌中添加Zn（OH）2沉淀的形成，但这个过程在过量的氢氧化铵形成四胺锌配合物。然后，将基板浸渍在蒸馏水中，在90个温度下，高温促进了氧化锌薄膜的粘附。在第一制备阶段，氨-锌离子络合物吸附到基板表面上，并在第二制备阶段，氢氧化的前体溶液的氢氧化物吸附到表面上，并与吸附的锌物种反应生成氧化锌，这反过来又被转换成氧化锌。有一些不溶性锌物种在反应液中含有OH-，NH3，Zn2+离子。