The flame reaction is a very old qualitative analysis, when the metal compound combustion in the flame, the heat of the flame so that the atomic internal electron gasified absorb enough energy to an excited state (excited state), when the electron returns to the ground state when (ground state), will issue a specific spectral lines. Different atoms tend to produce different wavelengths of the spectrum (emission spectrum). And the wavelength of light emitted in the visible range (wavelength of about 390nm ~ 770nm).
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